柳洁,沈德来,严锐锋,等. 卡瓦下座用表面改性可溶性镁合金耐腐蚀性能研究[J]. 石油钻探技术,2024, 52(1):1-10. DOI: 10.11911/syztjs.2024011
引用本文: 柳洁,沈德来,严锐锋,等. 卡瓦下座用表面改性可溶性镁合金耐腐蚀性能研究[J]. 石油钻探技术,2024, 52(1):1-10. DOI: 10.11911/syztjs.2024011
LIU Jie, SHEN Delai, YAN Ruifeng, et al. Study on corrosion resistance of surface-modified magnesium alloy for slip base [J]. Petroleum Drilling Techniques,2024, 52(1):1-10. DOI: 10.11911/syztjs.2024011
Citation: LIU Jie, SHEN Delai, YAN Ruifeng, et al. Study on corrosion resistance of surface-modified magnesium alloy for slip base [J]. Petroleum Drilling Techniques,2024, 52(1):1-10. DOI: 10.11911/syztjs.2024011

卡瓦下座用表面改性可溶性镁合金耐腐蚀性能研究

Study on Corrosion Resistance of Surface-Modified Magnesium Alloy for Slip Base

  • 摘要: 采用可溶性镁合金制作的节流器卡瓦下座,在井下服役过程中常因其降解速率过快而引起节流器失效,为此对可溶性镁合金表面进行了改性。为了解可溶性镁合金表面改性后的耐腐蚀性能,采用扫描电子显微镜观察了表面改性镁合金腐蚀前后表面的微观结构,采用X射线衍射仪和红外光谱仪分析了表面改性镁合金表腐蚀前后的物相结构,通过电化学试验和浸泡失重试验评价了其在pH值为3.0,7.2和9.0模拟井液中的耐腐蚀性能。与镁合金相比,在不同pH值的模拟井液中,表面改性镁合金的腐蚀电位均正移了约1.1 V,腐蚀电流密度均降低了3个数量级,腐蚀速率均降低了约3 mm/a;与pH值为7.2的模拟井液相比,在pH值为3的模拟井液中,表面改性镁合金的电荷转移电阻从9.13×106 Ω·cm2降至1.91×106 Ω·cm2。研究表明,与镁合金相比,表面改性镁合金在pH值为3.0,7.2和9.0模拟井液中的耐腐蚀性能均显著提高,但其在酸性模拟井液中的耐腐蚀性能大程度降低,易降解。对表面改性镁合金卡瓦下座节流器进行了现场试验,试验表明,表面改性镁合金卡瓦下座的承压性能、耐腐蚀性能满足要求,且其易于打捞。研究和现场试验结果均表明,表面改性镁合金的耐腐蚀性能满足可溶性卡瓦下座的要求,为其应用于井下节流器提供了依据。

     

    Abstract: In order to solve the problem of throttling failure caused by high degradation rate during the operation of the soluble Cava outlet, by modifying the surface of soluble magnesium alloy used in Cava, the microstructure and phase composition of the surface modified magnesium alloy were characterized by Sem, XRD and FT-IR, the mechanical properties of surface modified magnesium alloy and its corrosion resistance in simulated well fluids with different pH values (3,7.2,9) were analyzed.The corrosion potential of the modified magnesium alloy in the simulated well fluid with different pH values is positive shifted by about 1.1V, the corrosion current density is reduced by 3 orders of magnitude, and the degradation rate is reduced by about 6.44mm/y; Compared with the simulated well liquid with pH of 7.2, the charge transfer resistance Rct of the surface modified magnesium alloy in the simulated well fluid with pH of 3 decreases from 9.13×106 Ω·cm2 to 1.91×106 Ω·cm2. The results show that the corrosion resistance of the modified magnesium alloy in the three pH simulated well fluids is significantly improved, but the corrosion resistance in the acid simulated well fluids is the worst. After four months of on-site application, the lower soluble throttles in the Cava river delta have met the expected delivery and salvage requirements. The research results provide theoretical and experimental references for the use of soluble slip lower seats in the production of throttling devices.

     

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