油基钻井液用固体乳化剂的研制与评价

张建阔; 王旭东; 郭保雨; 何兴华; 王俊; 杨龙波

doi:10.11911/syztjs.201604011

油基钻井液用固体乳化剂的研制与评价

doi: 10.11911/syztjs.201604011

1.
中石化胜利石油工程有限公司黄河钻井总公司, 山东东营 257064;
2.
中石化胜利石油工程有限公司钻井工程技术公司, 山东东营 257064

基金项目:

中国石化集团科技攻关项目“可逆乳化钻井液技术研究”（编号：JP15011）、“油基钻井液现场制备和应用关键技术研究”（编号：JP13011）和中石化胜利石油工程有限公司博士后项目“油基钻井液用乳化剂的研究”（编号：GKB1220）的部分研究内容。

详细信息

作者简介:
张建阔(1974-),男,河北保定人,1999年毕业于大庆石油学院石油工程专业,高级工程师,主要从事钻井工程管理与技术管理工作。E-mailzhangjiankuo.slyt@sinopec.com。

中图分类号: TE254⁺.4
计量
- 文章访问数: 3644
- HTML全文浏览量: 53
- PDF下载量: 4534
- 被引次数: 0
出版历程
- 收稿日期: 2015-07-30
- 修回日期: 2016-06-03
- 刊出日期: 1900-01-01

Development and Evaluation of a Solid Emulsifier for Oil Based Drilling Fluid

1.
Huanghe Drilling Company, Sinopec Shengli Oilfield Service Corporation, Dongying, Shandong, 257064, China;
2.
Drilling Engineering Company, Sinopec Shengli Oilfield Service Corporation, Dongying, Shandong, 257064 China

摘要

摘要: 为解决油基钻井液常用液态乳化剂黏度高、流动性差，而常见固体乳化剂乳化效果差、制备步骤复杂的问题，通过简单的酰胺化反应制备了乳化能力强的油基钻井液用固体乳化剂EmuL-S。利用红外光谱分析了其结构，通过电稳定性、乳化率、析液量以及光学显微镜等手段考察了其乳化性能，并评价了以该乳化剂为基础配制的油基钻井液的性能。结果表明：固体乳化剂EmuL-S中含有设计要求的基团；当油水比为80∶20、固体乳化剂EmuL-S加量为3.3%时，形成的油包水乳状液的破乳电压大于1 000 V，乳化率大于90%，析液量小于0.7 mL，而且能抗180℃的高温；以固体乳化剂EmuL-S为基础配制的油基钻井液，密度最高可达到2.0 kg/L，抗温能力达到180℃，沉降稳定性高、流变性能优异，动塑比在0.21以上，破乳电压大于800 V，能抗15%水、15%劣质土、9%岩屑以及9% CaCl2的污染。研究表明，固体乳化剂EmuL-S具有优异的乳化能力和抗高温能力，并且具有制备简单、易于工业化生产的特点，可以解决现有乳化剂存在的问题。
- 油基钻井液 /
- 固体乳化剂 /
- 表面活性剂 /
- 钻井液性能
Abstract: Due to the fact that oil based drilling fluid liquid emulsifiers possess high viscosity and poor mobility, and the common solid emulsifiers have poor emulsification effect and complicated preparation procedure, a solid emulsifier EmuL-S with strong emulsifying ability in oil based drilling fluid has been developed by simple amidation reaction. Its structure was analyzed by using an infrared spectrum, and the emulsifying properties were investigated by means of electrical stability, emulsification rate, the amount of liquid dropout and optical microscopy. The performance of oil based drilling fluid containing the new emulsifier was evaluated. The results showed that the solid emulsifier EmuL-S contains the required group in the design. When the oil-water ratio is 80:20, with a solid emulsifier EmuL-S dosage of 3.3%, the water-in-oil emulsion has a breaking voltage of greater than 1000 V, the emulsion rate is greater than 90%, the amount of liquid dropout is less than 0.7mL, and the temperature is resistant to 180℃. The oil based drilling fluids with EmuL-S has a density up to 2.0 kg/L, temperature resistance is up to 180℃, with high sedimentation stability, excellent rheological properties, ratio of YP/PV is higher than 0.21, and the breaking voltage is greater than 800 V. Its pollution resistance capacities are at 15% water, 15% inferior soil, 9% cuttings and 9% CaCl2. Studies showed that the solid emulsifier EmuL-S has excellent emulsifying ability and high temperature resistance capability, and has the advantages of easy preparation and mass production, which can address the problems that exist in conventional emulsifiers.
- oil based drilling fluid /
- solid emulsifier /
- surfactant /
- drilling fluid property

HTML全文

参考文献(21)

[1]	路保平.中国石化页岩气工程技术进步及展望[J].石油钻探技术,2013,41(5):1-8.LU Baoping.Sinopec engineering technical advance and its developing tendency in shale gas[J].Petroleum Drilling Techniques,2013,41(5):1-8.
[2]	王中华.国内外超高温高密度钻井液技术现状与发展趋势[J].石油钻探技术,2011,39(2):1-7.WANG Zhonghua.Status and development trend of ultra-high temperature and high density drilling fluid at home and abroad[J].Petroleum Drilling Techniques,2011,39(2):1-7.
[3]	林永学,王显光.中国石化页岩气油基钻井液技术进展与思考[J].石油钻探技术,2014,42(4):7-13.LIN Yongxue,WANG Xianguang.Development and reflection of oil based drilling fluid technology for shale gas of Sinopec[J].Petroleum Drilling Techniques,2014,42(4):7-13.
[4]	王显光,李雄,林永学.页岩水平井用高性能油基钻井液研究与应用[J].石油钻探技术,2013,41(2):17-22.WANG Xianguang,LI Xiong,LIN Yongxue.Research and application of high performance oil base drilling fluid for shale horizontal wells[J].Petroleum Drilling Techniques,2013,41(2):17-22.
[5]	王中华.国内外油基钻井液研究与应用进展[J].断块油气田,2011,18(4):533-537.WANG Zhonghua.Research and application progress of oil based drilling fluid at home and abroad[J].Fault-Block OilGas Field,2011,18(4):533-537.
[6]	舒福昌,岳前升,黄红玺,等.新型无水全油基钻井液[J].断块油气田,2008,15(3):103-104.SHU Fuchang,YUE Qiansheng,HUANG Hongxi,et al.A new water-free oil based drilling fluid[J].Fault-Block OilGas Field,2008,15(3):103-104.
[7]	KIRSNER J,MILLER J,BRACKEN J.Additive for oil based drilling fluids:US7008907[P].2006-03-07.
[8]	王旭东,郭保雨,张海青,等.抗高温油包水型乳化剂的研制与应用[J].钻井液与完井液,2013,30(4):9-12.WANG Xudong,GUO Baoyu,ZHANG Haiqing,et al.Research and application on high temperature W/O emulsifier[J].Drilling FluidCompletion Fluid,2013,30(4):9-12.
[9]	王旭东,郭保雨,陈二丁,等.油基钻井液用高性能乳化剂的研制与评价[J].钻井液与完井液,2014,31(6):1-4.WANG Xudong,GUO Baoyu,CHEN Erding,et al.Development and evaluation of a high performance oil base mud emulsifier[J].Drilling FluidCompletion Fluid,2014,31(6):1-4.
[10]	梁大川,黄进军,崔茂荣,等.抗高温高密度低毒油包水钻井液的乳化剂优选和研制[J].西南石油学院学报,2000,22(3):74-77. LIANG Dachuan,HUANG Jinjun,CUI Maorong,et al.Optimization and development of emulsifiers used in invert oil-emulsion drilling fluid with high temperature,high density and low toxicity[J].Journal of Southwest Petroleum Institute,2000,22(3):74-77.
[11]	YU H,STEICHEN D S,JAMES A D,et al.Polyamide emulsifier based on polyamines and fatty acid/carboxylic acid for oil based drilling fluid applications:US7432230[P].2011-12-15.
[12]	MILLER J J.Metallic soaps of modified fatty acids and rosin acids and methods of making and using same:US7432230[P].2008-10-07.
[13]	HURD P W,FULTZ G D,JADHAV J Y.Spray dried emulsifier compositions,methods for their preparation,and their use in oil based drilling fluid compositions:US8927468[P].2015-01-06.
[14]	卢福伟,王伟忠,张松杰,等.Monte Carlo模拟设计油基钻井液乳化剂结构[J].钻井液与完井液,2013,30(4):13-14,18.LU Fuwei,WANG Weizhong,ZHANG Songjie,et al.Molecular design of oil based drilling fluid emulsifiers by Monte Carlo simulation[J].Drilling FluidCompletion Fluid,2013,30(4):13-14,18.
[15]	覃勇,蒋官澄,邓正强,等.抗高温油基钻井液主乳化剂的合成与评价[J].钻井液与完井液,2016,33(1):6-10.QIN Yong,JIANG Guancheng,DENG Zhengqiang,et al.Synthesis and evaluation of a primary emulsifier for high temperature oil base drilling fluid[J].Drilling FluidCompletion Fluid,2016,33(1):6-10.
[16]	中石化胜利石油工程有限公司钻井工程技术公司.一种油基钻井液用固体乳化剂及制备方法以及在油基钻井液的应用:CN103980869A[P].2014-08-13.Drilling Engineering and Technology Company,Sinopec Shengli Oilfield Service Corporation.Solid emulsifier for oil base drilling fluid and preparation method as well as application in oil base drilling fluid:CN103980869A[P].2014-08-13.
[17]	MENGER F M,LINAU C A.Gemini-surfactants:synthesis and properties[J].Journal of the American Chemical Society,1991,113(4):1451-1452.
[18]	ZANA R,XIA J.Gemini surfactants:synthesis,interfacial and solution-phase behavior,and applications[M].New York:Marcel Dekker Inc,2004:301-321.
[19]	HAN Yuchun,WANG Yilin.Aggregation behavior of Gemini surfactants and their interaction with macromolecules in aqueous solution[J].Physical Chemistry Chemical Physics,2011,13(6):1939-1956.
[20]	MAHMOUD S A,DARDIR M M.Synthesis and evaluation of a new cationic surfactant for oil-well drilling fluid[J].Journal of Surfactants and Detergents,2011,14(1):123-130.
[21]	侯业贵.低芳烃油基钻井液在页岩油气水平井中的应用[J].钻井液与完井液,2013,30(4):21-24.HOU Yegui.Application on low aromatic hydrocarbon oil based drilling fluid in shale oil and gas wells[J].Drilling FluidCompletion Fluid,2013,30(4):21-24.

[1]	王志远, 黄维安, 范宇, 李萧杰, 王旭东, 黄胜铭. 长宁区块强封堵油基钻井液技术研究及应用, 石油钻探技术. doi: 10.11911/syztjs.2021039
[2]	王建华, 闫丽丽, 谢盛, 张家旗, 杨海军. 塔里木油田库车山前高压盐水层油基钻井液技术, 石油钻探技术. doi: 10.11911/syztjs.2020007
[3]	张雄, 余进, 毛俊, 刘祖磊. 准噶尔盆地玛东油田水平井高性能油基钻井液技术, 石油钻探技术. doi: 10.11911/syztjs.2020106
[4]	张卫, 路保平, 王保良, 李新, 陆军轶, 冀海峰. 适用于油基钻井液的随钻电阻率成像测井方法, 石油钻探技术. doi: 10.11911/syztjs.2019009
[5]	王友启. 高钙镁油藏烷醇酰胺类表面活性剂及其复配体系驱油性能研究, 石油钻探技术. doi: 10.11911/syztjs.2018063
[6]	舒曼, 赵明琨, 许明标. 涪陵页岩气田油基钻井液随钻堵漏技术, 石油钻探技术. doi: 10.11911/syztjs.201703004
[7]	李胜, 夏柏如, 林永学, 王显光, 韩秀贞. 焦页54-3HF井低油水比油基钻井液技术, 石油钻探技术. doi: 10.11911/syztjs.201701009
[8]	王满学, 何静, 王永炜. 耐高温低碳烃无水压裂液室内研究, 石油钻探技术. doi: 10.11911/syztjs.201704016
[9]	解宇宁. 低毒环保型油基钻井液体系室内研究, 石油钻探技术. doi: 10.11911/syztjs.201701008
[10]	凡帆, 王京光, 蔺文洁. 长宁区块页岩气水平井无土相油基钻井液技术, 石油钻探技术. doi: 10.11911/syztjs.201605006
[11]	王富华, 李雪雨, 赵海艳, 王路一. 基于马氏漏斗黏度的油基钻井液表观黏度预测方法, 石油钻探技术. doi: 10.11911/syztjs.201605010
[12]	林永学, 王显光, 李荣府. 页岩气水平井低油水比油基钻井液研制及应用, 石油钻探技术. doi: 10.11911/syztjs.201602005
[13]	张雪飞, 张伟, 徐新纽, 王俊文, 李君, 阮彪. 准噶尔盆地南缘H101井高密度油基钻井液技术, 石油钻探技术. doi: 10.11911/syztjs.201601007
[14]	李洪, 李治平, 王香增, 王才, 白瑞婷. 表面活性剂对低渗透油藏渗吸敏感因素的影响, 石油钻探技术. doi: 10.11911/syztjs.201605017
[15]	李建成, 关键, 王晓军, 孙延德, 鲁政权, 任艳. 苏53区块全油基钻井液的研究与应用, 石油钻探技术. doi: 10.11911/syztjs.201405011
[16]	林永学, 王显光. 中国石化页岩气油基钻井液技术进展与思考, 石油钻探技术. doi: 10.3969/j.issn.1001-0890.2014.04.002
[17]	万绪新. 渤南区块页岩油地层油基钻井液技术, 石油钻探技术. doi: 10.3969/j.issn.1001-0890.2013.06.009
[18]	何振奎. 泌页HF1井油基钻井液技术, 石油钻探技术. doi: 10.3969/j.issn.1001-0890.2012.04.007
[19]	王琳, 林永学, 杨小华, 蔡利山, 柴龙. 不同加重剂对超高密度钻井液性能的影响, 石油钻探技术. doi: 10.3969/j.issn.1001-0890.2012.03.010
[20]	蓝强, 李公让, 张敬辉, 张虹, 何兴贵, 刘宝峰. 石蜡纳米乳液的性能影响因素及低能乳化法制备, 石油钻探技术. doi: 10.3969/j.issn.1001-0890.2012.01.012